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Chemical sediments from the Early Eocene Green River Formation can be used for assessing hydroclimate and basin evolution during their deposition. The Wilkins Peak Member (WPM) of the Green River Formation contains a relatively continuous record of perennial closed-basin saline lake deposition in the Bridger Basin, southwest Wyoming, from approximately 51.6 to 49.8 Ma. The volumes and paragenesis of authigenic chemical sediments in the WPM are intrinsically related to the chemical evolution of basin brines. The geographic distribution of those chemical sediments across the Bridger Basin relates to the syn- and post-depositional tectonic history of the basin. In this study, we integrated thermodynamic modeling of chemical evolution of lake brines with chemostratigraphic and lithostratigraphic interpretations of the basin-center Solvay S-34-1 core to evaluate physical and chemical changes to and within ancient Lake Gosiute during the Early Eocene. Fine-scale X-ray fluorescence (XRF) scanning along the length of the core provides a high-resolution chemical stratigraphy of the WPM. Thermodynamic modeling of the evaporation of hypothetical inflow waters and lake brines yield predicted sequences of evaporite minerals, allowing estimation of the salinities and evaporated volumes of water required to reach saturation with respect to observed mineral deposits from the basin. The spatial distributions of bedded evaporites allow us to investigate tectonic changes to the basin during and after the deposition of the WPM. Here, we integrate these data to interpret changes in lake-level, salinity, and hydroclimate of ancient Lake Gosiute during the Early Eocene. 

Abstract The Green River Formation of Wyoming, USA, is host to the world’s largest known lacustrine sodium carbonate deposits, which accumulated in a closed basin during the early Eocene greenhouse. Alkaline brines are hypothesized to have been delivered to ancient Gosiute Lake by the Aspen paleoriver that flowed from the Colorado Mineral Belt. To precisely trace fluvial provenance in the resulting deposits, we conducted X-ray fluorescence analyses and petrographic studies across a suite of well-dated sandstone marker beds of the Wilkins Peak Member of the Green River Formation. Principal component analysis reveals strong correlation among elemental abundances, grain composition, and sedimentary lithofacies. To isolate a detrital signal, elements least affected by authigenic minerals, weathering, and other processes were included in a principal component analysis, the results of which are consistent with petrographic sandstone modes and detrital zircon chronofacies of the basin. Sandstone marker beds formed during eccentricity-paced lacustrine lowstands and record the migration of fluvial distributary channel networks from multiple catchments around a migrating depocenter, including two major paleorivers. The depositional topography of these convergent fluvial fans would have inversely defined bathymetric lows during subsequent phases of lacustrine inundation, locations where trona could accumulate below a thermocline. Provenance mapping verifies fluvial connectivity to the Aspen paleoriver and to sources of alkalinity in the Colorado Mineral Belt across Wilkins Peak Member deposition, and shows that the greatest volumes of sediment were delivered from the Aspen paleoriver during deposition of marker beds A, B, D, and I, each of which were deposited coincident with prominent “hyperthermal” isotopic excursions documented in oceanic cores. 

Abstract Lake Magadi is an internally drained, saline and alkaline terminal sump in the southern Kenya Rift. Geochemistry of samples from an ~200 m core representing the past ~1 m.y. of the lake's history shows some of the highest concentrations of transition metals and metalloids ever reported from lacustrine sediment, including redox-sensitive elements molybdenum, arsenic, and vanadium. Elevated concentrations of these elements represent times when the lake's hypolimnion was euxinic—that is, anoxic, saline, and sulfide-rich. Euxinia was common after ca. 700 ka, and after that tended to occur during intervals of high orbital eccentricity. These were likely times when high-frequency hydrologic changes favored repeated episodes of euxinia and sulfide precipitation. High-amplitude environmental fluctuations at peak eccentricity likely impacted water balance in terrestrial habitats and resource availability for early hominins. These are associated with important events in human evolution, including the first appearance of Middle Stone Age technology between ca. 500 and 320 ka in the southern Kenya Rift.